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Creators/Authors contains: "Reed, Christopher"

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  1. ; ; ; ; ; ; ; (, Chemical Science)
    57Fe nuclear resonance vibrational spectroscopy (NRVS) is used to study the tetranuclear iron clusters bearing a terminal Fe(iii)–O/OH moiety. The redox states of the three remote basal iron sites modulate the Fe(iii)–O/OH vibrational frequencies. 
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  2. ; ; ; (, Chemical Communications)
    The synthesis of (thiolfan*)Zr(NEt 2 ) 2 (thiolfan* = 1,1′-bis(2,4-di- tert -butyl-6-thiophenoxy)ferrocene) and its catalytic activity for intramolecular hydroamination are reported. In situ oxidation and reduction of the metal complex results in reactivity towards different substrates. The reduced form of (thiolfan*)Zr(NEt 2 ) 2 catalyzes hydroamination reactions of primary aminoalkenes, whereas the oxidized form catalyzes hydroamination reactions of secondary aminoalkenes. 
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